KINETIC STUDY OF DIRECT PHOTOLYSIS OF FOOD AND TEXTILE COLORS IN FLOW PHOTOREACTOR
DOI:
https://doi.org/10.47820/recima21.v4i3.2928Keywords:
Photobleaching. Direct photolysis. Ultraviolet Radiation. Indigotine Blue. Ponceau Red 4 R. Methylene Blue.Abstract
Wastewater from industries (food, textiles and leather) that use dyes in their production process are potential sources of pollution of water bodies. Effluents containing dyes modify the physical-chemical and biological properties of the aquatic environment, as they have a high load of organic matter and intense coloring. Environmental contamination is aggravated because these colored effluents are difficult to remove through the natural process of biodegradation. In this work, the direct photolysis process using ultraviolet radiation was used to treat solutions of food dyes, indigotine blue and ponceau red 4R, and a text dye, methylene blue. The experiments were carried out in a cylindrical photoreactor made of stainless steel with a solution recirculation system using an electropump. The photoreactor consists of a medium pressure mercury vapor lamp. The dye solutions were analyzed by ultraviolet and visible spectroscopy before the irradiation process and at different time intervals during irradiation. The results obtained indicate that direct photolysis is efficient for photobleaching of indigotine blue, ponceau red 4R and methylene blue dyes. The efficiency of the photobleaching process was 96% for indigo carmine blue with 140 minutes of irradiation, 89% for ponceau red 4R with 280 minutes of irradiation and 72% for methylene blue with 660 minutes of irradiation.
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ANVISA. Ministério da Saúde, Agência Nacional de Vigilância Sanitária. Resolução nº 899, de 29 de maio 2003. Diário Oficial da União, p. 1–22, 2003. https://www20.anvisa.gov.br/coifa/pdf/rdc166.pdf.
ANVISA. Ministério da Saúde, Agência Nacional de Vigilância Sanitária. Resolução nº 388, de 05 de agosto de 1999. Diário Oficial da União. p. 1–9, 1999.
AZZEZ, F.; AL-HETLANI, E.; ARAFA, M.; ABDELMONEM, Y.; ABDEL NAZEER, A.; AMIN, O. M.; MADKOUR, M. The efect of surface charge charge photocatalytic degradation of methylene blue dye using chargeable titania nanoparticles. Scientific Reports, , p. 9, 2018. https://doi.org/10.1038/s441598-018-25673-5.
BENINCÁ, C. Degradação do corante alimentício ponceau 4R e tratamento de efluente de uma indústria de alimentos utilizando processos oxidativos avançados. 2012. 125 f. Universidade Federal do Paraná, Curitiba - PR, Brasil, 2012.
BENJELLOUN, M.; MIYAH, Y.; AKDEMIR EVRENDILEK, G.; ZERROUQ, F.; LAIRINI, S. Recent Advances in Adsorption Kinetic Models: Their Application to Dye Types. Arabian Journal of Chemistry, vol. 14, no. 4, p. 103031, 2021. DOI 10.1016/j.arabjc.2021.103031. Available at: https://doi.org/10.1016/j.arabjc.2021.103031.
BENKHAYA, S.; M’RABET, S.; EL HARFI, A. Classifications, properties, recent synthesis and applications of azo dyes. Heliyon, vol. 6, no. 1, 2020. https://doi.org/10.1016/j.heliyon.2020.e03271.
BERRADI, M.; HSISSOU, R.; KHUDHAIR, M.; ASSOUAG, M.; CHERKAOUI, O.; EL BACHIRI, A.; EL HARFI, A. Textile finishing dyes and their impact on aquatic environs. Heliyon, vol. 5, p. 11, 2019. https://doi.org/https://doi.org/10.1016/j.heiyon.2019.e02711.
CASTILHOS, S. Catalisadores óxidos, suportados e sol-gel aplicados na fotodescoloração do corante vermelho ponceau 4 R e na fotodegradação da cafeína. 2018. 203 f. Universidade Estadual de Maringá, 2018.
CONAMA. Conselho Nacional do Meio Ambiente. Resolução Conama n° 357, de 17 de março de 2005. 2005. http://www.mma.gov.br/port/conama/res/res05/res35705.pdf.
CONAMA. Conselho Nacional do Meio Ambiente. Resolução n° 430, 13 de maio de 2011. Ministério do Meio Ambiente, p. 6, 2011.
CRINI, G.; TORRI, G.; LICHTFOUSE, E.; KYZAS, G. Z.; WILSON, L. D.; MORIN, N. Dye removal by biosorption using cross ‑ linked chitosan ‑ based hydrogels. Environmental Chemistry Letters, vol. 17, p. 1645–1666, 2019. https://doi.org/doi.org/10.1007/s10311-019-00903-y
ELSAYED, B. A.; MOHAMED, W.; EL-SAYED, B. A.; IBRAHIM, I. A.; MOHAMED, W. A. A.; AHMED, M. A. M. Synthesis and Characterization of Crystalline Nano TiO 2 and ZnO and their Effects on the Photodegradation of Indigo Carmine Dye Both of them View project Hydrogen production by reforming processes of oxygenates compunds View project Synthesis and Charact. International Journal of Advanced Engineering and Nano Technology (IJAENT), no. 2, p. 2347–6389, 2015.https://www.researchgate.net/publication/291166349.
FARTODE, A. P.; PARWATE, D. V. UV Photolytic Decolorization Study of Synthetic Waste Water Containing Indigo Carmine Dye in Presence of H 2 O 2. International Journal of Chemical and Physical Sciences UV, vol. 3, no. 3, p. 22–31, 2014.
GRČIĆ, I.; PAPIĆ, S.; MESEC, D.; KOPRIVANAC, N.; VUJEVIĆ, D. The kinetics and efficiency of UV assisted advanced oxidation of various types of commercial organic dyes in water. Journal of Photochemistry and Photobiology A: Chemistry, vol. 273, p. 49–58, 2014. https://doi.org/10.1016/j.jphotochem.2013.09.009.
GUPTA, V. K.; JAIN, R.; NAYAK, A.; AGARWAL, S.; SHRIVASTAVA, M. Removal of the hazardous dye-Tartrazine by photodegradation on titanium dioxide surface. Materials Science and Engineering C, vol. 31, no. 5, p. 1062–1067, 2011. DOI 10.1016/j.msec.2011.03.006. Available at: http://dx.doi.org/10.1016/j.msec.2011.03.006
HOSSEIN MASOUMBEIGI, A. R. Removal of Methylene Blue ( MB ) dye from synthetic wastewater using UV / H2O2 advanced oxidation process. Journal of Health Policy an Sustainable Health, vol. 2, no. 1, p. 160–166, 2015.
KHAN, I.; SAEED, K.; ZEKKER, I.; ZHANG, B.; HENDI, A. H.; AHMAD, A.; AHMAD, S.; ZADA, N.; AHMAD, H.; SHAH, L .A.; et al. Review on Methylene Blue: Its Properties, Uses, Toxicity and Photodegradation. Water, 14, 242, 2022.
KLEIN, F.; SCHARDONG, G.; STULP, S. Degradação de corantes por UV/H202-Aplicações de fotodegradação no estudo de tratamento de efuentes. Resvita Destaques Acadêmicos, vol. 2, p. 33–38, 2010.
LEMOS, P. J. H. C.; BATISTA, T.; MACHADO, D. S. Fotodegradação de Azul de Metileno por Óxidos Incorporados em Argila Sintética. Revista Processos Químicos, vol. 12, no. 23, p. 145–148, 2018. https://doi.org/10.19142/rpq.v12i23.448
MARMITT, S.; PIROTTA, L. V. APLICAÇÃO DE FOTÓLISE DIRETA E UV/H2 O2 A EFLUENTE SINTÉTICO CONTENDO DIFERENTES CORANTES ALIMENTÍCIOS. Química Nova na Escola, vol. 33, no. 2, p. 384–388, 2010.
MITTAL, J. Permissible Synthetic Food Dyes in India ∗. Resonance, vol. 25, no. 4, p. 567–577, 2020.
NAPOLITANO, G.; MOTTA, C. M.; AGNISOLA, C.; VENDITTI, P.; FASCIOLO, G.; FERRANDINO, I.; CAPRIELLO, T.; VITALE, E.; COSTANZO, G.; AVALLONE, B.; SIMONIELLO, P.; ARENA, C. Commercial Red Food Dyes Preparations Modulate the Oxidative State in Three Model Organisms (Cucumis sativus, Artemia salina, and Danio rerio). Environments - MDPI, vol. 9, no. 5, p. 1–18, 2022. https://doi.org/10.3390/environments9050063
PAMULA, A. S. P.; HUNG, Y. T.; PAUL, H. H. Treatment of combined acid black 48 and coffee wastewater by low-cost adsorbents. Environmental Research, Engineering and Management, vol. 76, no. 3, p. 47–61, 2020. https://doi.org/10.5755/j01.erem.76.3.25338
REHMAN, F.; SAYED, M.; ALI, J.; SHAH, N. S.; KHAN, H. M. Oxidative removal of brilliant green by UV / S 2 O 82 ‒ , UV / HSO 5 ‒ and UV / H 2 O 2 processes in aqueous media : A comparative study. Journal of Hazardous Materials journal, vol. 357, no. June, p. 506–514, 2018.
REHMAN, R.; ABBAS, A.; MITU, L. Rapid photocatalytic degradation of methylene blue, tartrazine and brilliant green dyes by high-flux UV irradiation photolysis reactor. Bulgarian Chemical Communications, vol. 51, no. 3, p. 337–341, 2019. https://doi.org/10.34049/bcc.51.3.4683.
SÁ, F. P. de. Adsorção e Fotodegradação de Corantes , Amarelo Crepúsculo e Azul Brilhante , para Tratamento de Efluentes de Indústrias Alimentícias. 2013. 109 f. Universidade Federal de Goiás, Goiânia - Goiás, Brasil, 2013.
SÁ, F. P. de.; CUNHA, B. N.; NUNES, L. M. Effect of pH on the adsorption of Sunset Yellow FCF food dye into a layered double hydroxide (CaAl-LDH-NO3). Chemical Engineering Journal, vol. 215–216, p. 122–127, 2013. https://doi.org/10.1016/j.cej.2012.11.024
SALES, H. B.; BOUQUET, V.; DÉPUTIER, S.; OLLIVIER, S.; GOUTTEFANGEAS, F.; GUILLOUX-VIRY, M.; DORCET, V.; WEBER, I. T.; DE SOUZA, A. G.; DOS SANTOS, I. M. G. Sr1-xBaxSnO3 system applied in the photocatalytic discoloration of an azo-dye. Solid State Sciences, vol. 28, p. 67–73, 2014. https://doi.org/10.1016/j.solidstatesciences.2013.12.007
SARTAJ, S.; ALI, N.; KHAN, A.; MALIK, S.; BILAL, M.; KHAN, M.; ALI, N.; HUSSAIN, S.; KHAN, H. Performance evaluation of photolytic and electrochemical oxidation processes for enhanced degradation of food dyes laden wastewater. Water Science & Technology |, vol. 1, p. 1–14, 2020. https://doi.org/10.2166/wst.2020.182
SCREMIN, L. B. Adsorção de corantes têxteis aniônicos e catiônicos em resíduos do processamento de fios de algodão modificados quimicamente. 2015. 107 p. Universidade Tecnológica Federal do Paraná. Curitiba, Paraná, Brasil, 2015.
SOLTANI, T.; ENTEZARI, M. H. Journal of Molecular Catalysis A : Chemical Photolysis and photocatalysis of methylene blue by ferrite bismuth nanoparticles under sunlight irradiation. Journal of Molecular Catalysis A: Chemical, vol. 377, no. 3, p. 197–203, 2013.
SOUZA, D. R. de. Degradação da matéria orgânica proveniente de efluente de indústria de madeira, empregando fotocatálise e radiação solar. 2004. 89 f. Universidade Federal de Uberlândia, Uberlândia - Minas Gerais, Brasil, 2004.
ZANONI, M. V. B.; YANAMAKA, H. CORANTES Caracterização Química, Toxicológica, métodos de Detecção e Tratamento, 2016.
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